The behaviour of dissolved organic material,iron and manganese in estuarine mixing     

R.M. Moore  J.D. Burton  P.J.LeB. Williams  M.L. Young 《Geochimica et cosmochimica acta》1979,43(6):919-926

Fractionation by ultra-filtration of the dissolved organic material (DOM) in the River Beaulieu, with typical concentrations of dissolved organic carbon (DOC) of 7–8 mg C/l, showed it to be mainly in the nominal molecular weight range of 10³–10⁵, with 16–23% of the total DOC in the fraction > 10⁵. The molecular weight distribution of DOM in the more alkaline River Test (average DOC, 2 mg C/l) was similar. In the River Beaulieu water, containing 136–314 βg Fe/l in ‘dissolved’ forms, 90% or more of this Fe was in the nominal molecular weight fraction > 10⁵. Experiments showed that DOM of nominal molecular weight <10⁵ could stabilize Fe(III) in ‘dissolved’ forms. The concentrations of ‘dissolved’ Fe in the river water probably reflect the presence of colloidal Fe stabilized by organic material and this process may influence the apparent molecular weight of the DOM. Dissolved. Mn (100–136 βg/l) in the River Beaulieu was mainly in true solution, probably as Mn(II), with some 30% in forms of molecular weight greater than ca 10⁴.During mi xing in the Beaulieu Estuary, DOC and dissolved Mn behave essentially conservatively. This contrasts with the removal of a large fraction of the dissolved Fe (Holliday and LISS, 1976, Est. Coastal Mar. Sci. 4, 349–353). Concentrations of lattice-held Fe and Mn in suspended particulate material were essentially uniform in the estuary, at 3.2 and 0.012%, respectively, whereas the non-lattice held fractions decreased markedly with increase in salinity. For Mn the decrease was linear and could be most simply accounted for by the physical mixing of riverborne and marine participates, although the possibility that some desorption occurs is not excluded. The non-linear decrease in the concentration of non-lattice held Fe in particulates reflected the more complex situation in which physical mixing is accompanied by removal of material from the ‘dissolved’ fraction.  相似文献   

楚科奇海与加拿大海盆表层沉积物表观特征及其环境指示   总被引：1，自引：0，他引：1  

高爱国  王汝建  陈建芳  张德玉  张道建 《海洋地质与第四纪地质》2008,28(6)

通过对中国首次和第二次北极科学考察采集的表层沉积物的观察，根据沉积物的颜色和气味、砾石分布、底栖生物及贝壳分布特征的分析，探讨了该海区表层沉积物表观特征变化与有机质输入、沉积物的氧化还原状态的关系、底栖生物分布范围、冰筏碎屑的分布区域及与海流的关系，指出在研究区软体动物生长的北界位于73．5&#176;N，比浮游动物的北界约低2个纬度。冰筏碎屑的北界可作为融冰水的北界或永久冰区的南界，位置在77&#176;24′N附近。通过对沉积物表观特征的综合分析，结合研究区的海流特征，指出研究区的海流分布对沉积物分布有重要影响，尤其是两股不同性质的海流相遇，对西南部与东部两个区域的沉积物组成及性质具有较强的控制作用。  相似文献   

加拿大海盆北部营养盐限制作用研究   总被引：1，自引：1，他引：0  

李宏亮  陈建芳  高生泉  卢勇  金海燕  白有成  庄燕培  张海生 《海洋学报》2015,37(11):147-154

利用2008年夏季中国第三次北极科学考察获得的营养盐、叶绿素a、温度和盐度等数据资料,结合现场营养盐添加实验的结果讨论西北冰洋加拿大海盆北部营养盐对浮游植物生长的限制作用。结果表明:由于融冰水稀释作用,加拿大海盆B80站约20m深度存在较强的盐跃层,阻碍了水体上下混合。较低浓度的溶解无机氮(DIN)和硅酸盐(分别为0.31μmol/L和0.94μmol/L)以及严重偏离Redfield比值的N/P、N/Si比值(分别为0.42和0.32)表明加拿大海盆表层水体存在N和Si限制。根据现场营养盐加富实验各培养组叶绿素a浓度变化、营养盐吸收总量差异和浮游植物种群结构,进一步表明氮是北冰洋海盆首要限制营养盐,而Si则抑制了硅质生物的生长。同时,较小的硝酸盐半饱和常数(Ks)证明即使在营养盐充足的情况下北冰洋海盆浮游植物生长速率也处于较低水平。计算得到各培养组营养盐吸收比例(N/P比值)均大于Redfield比值,可能是培养实验过程中以微型、微微型浮游植物为主,硅藻等小型浮游植物为辅造成的。  相似文献   

Estimating Sea-Level Allowances for Atlantic Canada using the Fifth Assessment Report of the IPCC     

Li Zhai  Blair J.W. Greenan  John Hunter  Thomas S. James  Guoqi Han  Phillip MacAulay 《大气与海洋》2015,53(5):476-490

Abstract

Sea-level allowances at 22 tide-gauge sites along the east coast of Canada are determined based on projections of regional sea-level rise for the Representative Concentration Pathway 8.5 (RCP8.5) from the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR5) and on the statistics of historical tides and storm surges (storm tides). The allowances, which may be used for coastal infrastructure planning, increase with time during the twenty-first century through a combination of mean sea-level rise and the increased uncertainty of future projections with time. The allowances show significant spatial variation, mainly a consequence of strong regionally varying relative sea-level change as a result of glacial isostatic adjustment (GIA). A methodology is described for replacement of the GIA component of the AR5 projection with global positioning system (GPS) measurements of vertical crustal motion; this significantly decreases allowances in regions where the uncertainty of the GIA models is large. For RCP8.5 with GPS data incorporated and for the 1995–2100 period, the sea-level allowances range from about 0.5?m along the north shore of the Gulf of St. Lawrence to more than 1?m along the coast of Nova Scotia and southern Newfoundland.  相似文献   

An Evaluation of Temperature and Precipitation Surface-Based and Reanalysis Datasets for the Canadian Arctic, 1950–2010     

Maja Rapaić  Marko Markovic  Diane Chaumont 《大气与海洋》2015,53(3):283-303

The spatial and temporal consistency of seasonal air temperature and precipitation in eight widely used gridded observation-based climate datasets (CANGRD, CRU-TS3.1, CRUTEM4.1, GISTEMP, GPCC, GPCP, HadCRUT3, and UDEL) and eight reanalyses (20CR, CFSR, ERA-40, ERA-Interim, JRA25, MERRA, NARR, and NCEP2) was evaluated over the Canadian Arctic for the 1950–2010 period. The evaluation used the CANGRD dataset, which is based on homogenized temperature and adjusted precipitation from climate stations, as a reference. Dataset agreement and bias were observed to exhibit important spatial, seasonal, and temporal variability over the Canadian Arctic with the largest spread occurring between datasets over mountain and coastal regions and over the Canadian Arctic Archipelago. Reanalysis datasets were typically warmer and wetter than surface observation-based datasets, with CFSR and 20CR exhibiting biases in total annual precipitation on the order of 300?mm. Warm bias in 20CR exceeded 12°C in winter over the western Arctic. Analysis of the temporal consistency of datasets over the 1950–2010 period showed evidence of discontinuities in several datasets as well as a noticeable increase in dataset spread in the period after approximately 2000. Declining station networks, increased automation, and the inclusion of new satellite data streams in reanalyses are potential contributing factors to this phenomenon. Evaluation of trends over the 1950–2010 period showed a relatively consistent picture of warming and increased precipitation over the Canadian Arctic from all datasets, with CANGRD giving moistening trends two times larger than the multi-dataset average related to the adjustment of the station precipitation data. The study results indicate that considerable care is needed when using gridded climate datasets in local or regional scale applications in the Canadian Arctic.  相似文献   

Palynological evidence for Pennsylvanian (Late Carboniferous) vegetation change in the Sydney Coalfield,eastern Canada     

Tatyana K. Dimitrova  Erwin L. Zodrow  Christopher J. Cleal  Barry A. Thomas 《Geological Journal》2010,45(4):388-396

The palynology of clastic samples from seven stratigraphical levels in the late Moscovian Sydney Mines Formation, exposed along the shore at Bras d'Or, Nova Scotia, has been investigated. Most of the samples were from roof shales of major coals; the one sample that was not yielded a much higher proportion of pollen derived from extra‐basinal vegetation. The four stratigraphically lower roof shale samples yielded essentially similar palynological spectra, with 39 ± 4% lycophytes, 9 ± 4% sphenophylls, 23 ± 4% tree‐ferns, 12 ± 4% other ferns and 5 ± 3% cordaites. The palynology of the upper part of the investigated succession suggests a shift in vegetation towards one favouring more marattialean tree‐ferns, cordaites and conifers, and fewer lycophytes. This correlates with changes in drainage patterns as the alluvial plain migrated seawards and thus changed water tables. No evidence was found to suggest significant climate change at this time. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Sr isotopic composition of Paleoproterozoic C-rich carbonate rocks: The Tulomozero Formation,SE Fennoscandian Shield     

A.B. Kuznetsov  V.A. Melezhik  I.M. Gorokhov  N.N. Melnikov  G.V. Konstantinova  E.P. Kutyavin  T.L. Turchenko 《Precambrian Research》2010

Rb–Sr systematics has been studied in ¹³C-rich carbonate rocks of the Paleoproterozoic (2.09 ± 0.07 Ga) Tulomozero Formation in the northern Onega Lake area, the SE Fennoscandian Shield. The formation is divided into eight members (A–F) consisting of greenschist-facies-grade, variegated sandstones, siltstones, mudstones, stromatolitic dolostones and subordinate crystalline limestones. Samples of carbonate rocks were obtained from two overlapping drillholes intersecting the entire thickness of the Tulomozero Formation. Prior to isotope analysis, the rocks powders were treated with 1N ammonium acetate for partial removal of the late epigenetic carbonate phases. Major resetting of the Rb–Sr systems in the Tulomozero carbonate rocks appears to take place during the Svecofennian regional metamorphic event, and it was screened by using Mn/Sr, Fe/Sr, Mg/Ca, and ¹⁸O/¹⁶O ratios. High Sr content (up to 2080 μg/g in limestones, and 530 μg/g in dolostones) coupled with low Fe/Mn (<0.40) ratios in the Tulomozero carbonate rocks of Members A, B (the lower part), D, F, and E are consistent with accumulation of original carbonate sediments in evaporitic lacustrine, playa, and sabkha environments. A decrease in the Sr content with concurrent increase in the Fe/Mn ratio (>0.40) in dolostones of the upper part of Member B, and of Members G and H is indicative of seawater influxes (sea transgression) into the Tulomozero basin. The ⁸⁷Sr/⁸⁶Sr values in the least altered (Mn/Sr < 2.0) marine dolostones are 0.70418–0.70442 and 0.70343–0.70409 for the earlier and late phases of the marine transgression, respectively. The decrease in the ⁸⁷Sr/⁸⁶Sr ratio in ca. 2.1 Ga seawater is attributable to an increase in hydrothermal flux Sr into the Palaeoproterozoic ocean.  相似文献   

世界页岩气勘探开发现状及对中国的启示   总被引：16，自引：3，他引：13  

李世臻  乔德武  冯志刚 《地质通报》2010,29(6):918-924

页岩气是一种潜在资源量巨大的非常规天然气资源,具有开采技术要求高、开采寿命长、稳产周期长的特点。近些年来,严峻的能源紧张形势和能源价格的快速增长,使页岩气资源在全世界受到了广泛的重视。回顾了美国页岩气勘探开发的历史,总结了美国的页岩气发育情况,跟踪了世界其他地区(加拿大、欧洲)包括中国页岩气研究的最新进展情况。根据前人的资料,认为中国南方海相页岩和北方盆地的湖相页岩具有巨大的页岩气资源潜力。鉴于页岩气是一种非常规能源,对其研究具有重大的现实意义,建议中国相关部门加大研究投入力度,尽快开展页岩气资源战略调查和选区研究工作,加强技术攻关创新、引进和国际合作,探讨中国现实国情下的页岩气相关政策,以早日实现页岩气在中国的商业性开发,促进经济快速发展。  相似文献   

Sedimentology and stratigraphy of the Lower Cretaceous Isachsen Formation: Ellef Ringnes Island,Sverdrup Basin,Canadian Arctic Archipelago     

《Marine and Petroleum Geology》2014

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An exploration for deep-sea fish sounds off Vancouver Island from the NEPTUNE Canada ocean observing system     

《Deep Sea Research Part I: Oceanographic Research Papers》2014

Our understanding of the significance of sound production to the ecology of deep-sea fish communities has improved little since anatomical surveys in the 1950s first suggested that sound production is widespread among slope-water fishes. The recent implementation of cabled ocean observatory networks around the world that include passive acoustic recording instruments provides scientists an opportunity to search for evidence of deep-sea fish sounds. We examined deep-sea acoustic recordings made at the NEPTUNE Canada Barkley Canyon Axis Pod (985 m) located off the west coast of Vancouver Island in the Northeast Pacific between June 2010 and May 2011 to determine the presence of fish sounds. A subset of over 300 5-min files was examined by selecting one day each month and analyzing one file for each hour over the 24 h day. Despite the frequent occurrence of marine mammal sounds, no examples of fish sounds were identified. However, we report examples of isolated unknown sounds that might be produced by fish, invertebrates, or more likely marine mammals. This finding is in direct contrast to recent smaller studies in the Atlantic where potential fish sounds appear to be more common. A review of the literature indicates 32 species found off British Columbia that potentially produce sound could occur in depths greater than 700 m but of these only Anoplopoma fimbria and Coryphaenoides spp. have been previously reported at the site. The lack of fish sounds observed here may be directly related to the low diversity and abundance of fishes present at the Barkley Canyon site. Other contributing factors include possible masking of low amplitude biological signals by self-generated noise from the platform instrumentation and ship noise. We suggest that examination of data both from noise-reduced ocean observatories around the world and from dedicated instrument surveys designed to search for deep-sea fish sounds to provide a larger-scale, more conclusive investigation into the role, or potential lack thereof, of sound production.  相似文献